Phthalocyanine-Based Single-Component Molecular Conductor [Mn(III)(Pc)(CN)]2O.
Inorg Chem
; 55(15): 7314-6, 2016 Aug 01.
Article
en En
| MEDLINE
| ID: mdl-27428928
ABSTRACT
A new manganese complex, [Mn(Pc)(CN)]2O, was prepared by an electrocrystallization method. This material is a single-component molecular conductor that displays semiconducting behavior with room temperature conductivity of 4.5 × 10(-3) S cm(-1). Furthermore, we observed negative magnetoresistance at room temperature due to interaction between conduction π electrons and localized d spins. X-ray structural analysis and IR absorption spectroscopy indicated structural disorder. The magnetic susceptibility measurements suggested the unequal spin states of two manganese atoms owing to this structural disorder.
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Colección:
01-internacional
Base de datos:
MEDLINE
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En
Revista:
Inorg Chem
Año:
2016
Tipo del documento:
Article
País de afiliación:
Japón