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Silver-promoted decarboxylative amidation of α-keto acids with amines.
Xu, Xiao-Lan; Xu, Wen-Tao; Wu, Ji-Wei; He, Jian-Bo; Xu, Hua-Jian.
Afiliación
  • Xu XL; School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, P. R. China. jbhe@hfut.edu.cn and School of Medical Science, Anhui Medical University, Hefei 230026, P. R. China.
  • Xu WT; School of Biological and Medical Engineering, Hefei University of Technology, Hefei 230009, P. R. China. hjxu@hfut.edu.cn.
  • Wu JW; School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, P. R. China. jbhe@hfut.edu.cn.
  • He JB; School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, P. R. China. jbhe@hfut.edu.cn.
  • Xu HJ; School of Biological and Medical Engineering, Hefei University of Technology, Hefei 230009, P. R. China. hjxu@hfut.edu.cn.
Org Biomol Chem ; 14(42): 9970-9973, 2016 Oct 25.
Article en En | MEDLINE | ID: mdl-27722669
ABSTRACT
A general and effective method for the synthesis of amides through decarboxylative amidation of α-keto acids with amines has been developed. The reaction proceeded smoothly to afford the corresponding amide products in good yield under air and shows excellent functional group tolerance. In addition, the protocol can be further applied in the synthesis of heterocyclic compounds like benzimidazoles.
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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2016 Tipo del documento: Article
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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2016 Tipo del documento: Article