Phototransformation of the Herbicide Propanil in Paddy Field Water.
Environ Sci Technol
; 51(5): 2695-2704, 2017 03 07.
Article
en En
| MEDLINE
| ID: mdl-28145687
ABSTRACT
When irradiated in paddy-field water, propanil (PRP) undergoes photodegradation by direct photolysis, by reactions with â¢OH and CO3â¢-, and possibly also with the triplet states of chromophoric dissolved organic matter. Irradiation also inhibits the nonphotochemical (probably biological) degradation of PRP. The dark- and light-induced pathways can be easily distinguished because 3,4-dichloroaniline (34DCA, a transformation intermediate of considerable environmental concern) is produced with almost 100% yield in the dark but not at all through photochemical pathways. This issue allows an easy assessment of the dark process(es) under irradiation. In the natural environment, we expect PRP photodegradation to be important only in the presence of elevated nitrate and/or nitrite levels, e.g., [NO3-] approaching 1 mmol L-1 (corresponding to approximately 60 mg L-1). Under these circumstances, â¢OH and CO3â¢- would play a major role in PRP phototransformation. Because flooded paddy fields are efficient denitrification bioreactors that can achieve decontamination of nitrate-rich water used for irrigation, irrigation with such water would both enhance PRP photodegradation and divert PRP dissipation processes away from the production of 34DCA, at least in the daylight hours.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Propanil
/
Agua
Idioma:
En
Revista:
Environ Sci Technol
Año:
2017
Tipo del documento:
Article
País de afiliación:
Italia