A meta-selective-C-H alkenylation of phenol-derivatives employing a traceless organosilicon template.
Chem Commun (Camb)
; 53(99): 13209-13212, 2017 Dec 12.
Article
en En
| MEDLINE
| ID: mdl-29147691
ABSTRACT
A traceless organosilicon template-directed meta-selective-C-H alkenylation of phenols was realized with good yields and high selectivities. The template was readily removable through F--promoted O-Si cleavage under extremely mild conditions or recyclable through a p-TSA catalyzed process. The product was successfully applied in the preparation of a series of meta-alkenylated aromatic compounds.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2017
Tipo del documento:
Article
País de afiliación:
China