Reversible Carboxylate Shift in a µ-Oxo Diferric Complex in Solution by Acid-/Base-Addition.
Inorg Chem
; 57(9): 5400-5405, 2018 May 07.
Article
en En
| MEDLINE
| ID: mdl-29633835
ABSTRACT
A reversible carboxylate shift has been observed in a µ-oxo diferric complex in solution by UV-vis-NIR and FTIR spectroscopy triggered by the addition of a base or an acid. A terminal acetate decoordinates upon the addition of a proton, resulting in a shift of the remaining terminal acetato to a µ-η1η1 bridge. The addition of a base restores the original structure containing only terminal acetates. The implications for metalloenzymes with carboxylate-bridged nonheme diiron active sites are discussed.
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01-internacional
Base de datos:
MEDLINE
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En
Revista:
Inorg Chem
Año:
2018
Tipo del documento:
Article
País de afiliación:
Alemania