Function-Oriented: The Construction of Lanthanide MOF Luminescent Sensors Containing Dual-Function Urea Hydrogen-Bond Sites for Efficient Detection of Picric Acid.
Chemistry
; 25(4): 1090-1097, 2019 Jan 18.
Article
en En
| MEDLINE
| ID: mdl-30426572
ABSTRACT
Two novel lanthanide metal-organic framework (Ln-MOF) luminescent sensors for the detection of picric acid have been successfully assembled. Following a function-oriented strategy, urea hydrogen-bonding functional sites were introduced into two MOF frameworks. A structural analysis indicated that the two MOFs have the exact same structure, namely 2D layers with diamond-shaped holes that are accumulated into a 3D framework through the hydrogen-bonding interactions between urea and carboxylate groups. Interestingly, only half of the urea units are involved in supporting the MOF framework through N-Hâ
â
â
O hydrogen-bonding interactions, whereas the other half are located in the pore channel and act as empty recognition sites. Abundant N-H urea bonds are present in the inner walls of three types of interpenetrating 1D channels. Luminescence studies revealed that the two Ln-MOFs exhibit high sensitivity, good selectivity, and a fast luminescence quenching response towards picric acid. In particular, the two Ln-MOFs can be simply and quickly regenerated, and exhibit excellent recyclability. In summary, we have successfully used a function-oriented strategy to achieve multiple functions in a ligand to construct lanthanide MOF luminescent sensors for the detection of picric acid, thereby providing a potential strategy for the future development of MOF luminescent sensors with a specific target.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Tipo de estudio:
Diagnostic_studies
Idioma:
En
Revista:
Chemistry
Asunto de la revista:
QUIMICA
Año:
2019
Tipo del documento:
Article
País de afiliación:
China