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Hydrophobic Polyoxometalate-Based Metal-Organic Framework for Efficient CO2 Photoconversion.
Li, Xiao-Xin; Liu, Jiang; Zhang, Lei; Dong, Long-Zhang; Xin, Zhi-Feng; Li, Shun-Li; Huang-Fu, Xue-Qing; Huang, Kai; Lan, Ya-Qian.
Afiliación
  • Li XX; School of Chemistry and Chemical Engineering , Southeast University , Nanjing 211189 , P. R. China.
  • Liu J; Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, College of Chemistry and Materials Science , Nanjing Normal University , Nanjing 210023 , P. R. China.
  • Zhang L; Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, College of Chemistry and Materials Science , Nanjing Normal University , Nanjing 210023 , P. R. China.
  • Dong LZ; Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, College of Chemistry and Materials Science , Nanjing Normal University , Nanjing 210023 , P. R. China.
  • Xin ZF; Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, College of Chemistry and Materials Science , Nanjing Normal University , Nanjing 210023 , P. R. China.
  • Li SL; Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, College of Chemistry and Materials Science , Nanjing Normal University , Nanjing 210023 , P. R. China.
  • Huang-Fu XQ; Institute of Molecular Engineering and Applied Chemistry , Anhui University of Technology , Ma'anshan 243002 , P. R. China.
  • Huang K; Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, College of Chemistry and Materials Science , Nanjing Normal University , Nanjing 210023 , P. R. China.
  • Lan YQ; Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, College of Chemistry and Materials Science , Nanjing Normal University , Nanjing 210023 , P. R. China.
ACS Appl Mater Interfaces ; 11(29): 25790-25795, 2019 Jul 24.
Article en En | MEDLINE | ID: mdl-31240910
A novel polyoxometalate (POM)-based metal-organic framework, TBA5[P2Mo16VMo8VIO71(OH)9Zn8(L)4] (NNU-29), was in situ synthesized and applied into CO2 photoreduction. The selection of porous material containing a reductive POM cluster is considered to be helpful for CO2 reduction; meanwhile, a hydrophobic-group-modified organic ligand enables NNU-29 to exhibit good chemical stability and restrains hydrogen generation to some extent. In the photocatalytic CO2 reduction, the yield of HCOO- reached 35.2 µmol in the aqueous solution with selectivity of 97.9% after 16 h.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2019 Tipo del documento: Article
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Appl Mater Interfaces Asunto de la revista: BIOTECNOLOGIA / ENGENHARIA BIOMEDICA Año: 2019 Tipo del documento: Article