Unexpected Formation of Hexasubstituted Arenes through a 2-fold Palladium-Mediated Ligand Arylation.

Wagen, Corin C; Ingoglia, Bryan T; Buchwald, Stephen L

Wagen, Corin C; Ingoglia, Bryan T; Buchwald, Stephen L.

Afiliación

Wagen CC; Department of Chemistry , Massachusetts Institute of Technology , Cambridge , Massachusetts 02139 , United States.
Ingoglia BT; Department of Chemistry , Massachusetts Institute of Technology , Cambridge , Massachusetts 02139 , United States.
Buchwald SL; Department of Chemistry , Massachusetts Institute of Technology , Cambridge , Massachusetts 02139 , United States.

J Org Chem ; 84(19): 12672-12679, 2019 10 04.

Article en En | MEDLINE | ID: mdl-31512875

ABSTRACT

ABSTRACT

A rearrangement reaction of biarylphosphine-supported Pd(II) complexes was employed to synthesize 1,3,5-triaryl 2,4,6-triisopropylbenzene compounds, a class of molecules that has not previously been reported. The strain of the central hexasubstituted ring was investigated via X-ray crystallography.

Asunto(s)

Calixarenos/síntesis química; Paladio/química; Calixarenos/química; Catálisis; Cristalografía por Rayos X; Ligandos; Modelos Moleculares; Estructura Molecular

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Paladio / Calixarenos Idioma: En Revista: J Org Chem Año: 2019 Tipo del documento: Article País de afiliación: Estados Unidos

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