Protection strategies for directionally-controlled synthesis of previously inaccessible metal-organic polyhedra (MOPs): the cases of carboxylate- and amino-functionalised Rh(ii)-MOPs.
Chem Commun (Camb)
; 55(85): 12785-12788, 2019 Nov 04.
Article
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| MEDLINE
| ID: mdl-31591620
ABSTRACT
Herein we report that strategic use of protecting groups in coordination reactions enables directional inhibition that leads to synthesis of highly functionalised metal-organic polyhedra (MOPs), rather than of the extended coordination networks. Using this approach, we functionalised two new porous cuboctahedral Rh(ii)-based MOPs with 24 peripheral carboxylic acid groups or 24 peripheral amino groups.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2019
Tipo del documento:
Article