Study of the properties and mechanism of deep reduction and efficient adsorption of Cr(VI) by low-cost Fe3O4-modified ceramsite.

ABSTRACT

To efficiently treat low-concentration chromium wastewater at low cost, adsorbent iron-modified ceramsite (FCM) was successfully prepared. The adsorbent was characterized by SEM, XRD, FT-IR, XPS, ζ potential and VSM. From the experimental results, the optimum adsorption pH, adsorbent dosage and adsorption time were 4, 1g/L and 120min, respectively. The percentage removal of Cr(VI) was 93% and the reduction efficiency of Cr(VI) was 74.3% when the concentration was 2mg/L. After 5cycles, using 0.1mol/L NaOH as the regeneration agent, the removal rate of Cr(VI) did not decrease significantly. Furthermore, the mechanism of deep reduction and adsorption, the process of regeneration, the kinetics and adsorption isotherms were also explored. This paper can provide theoretical and technical support for reducing the toxicity and the advanced treatment of hexavalent chromium.