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Visible-Light-Enabled Oxidative Coupling of Alkenes with Dialkylformamides To Access Unsaturated Amides.
Lu, Maojian; Lin, Zhaowei; Chen, Shanyi; Chen, Hongyou; Huang, Mingqiang; Cai, Shunyou.
Afiliación
  • Lu M; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry, Chemical Engineering, and Environment , Minnan Normal University , Zhangzhou 363000 , China.
  • Lin Z; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry, Chemical Engineering, and Environment , Minnan Normal University , Zhangzhou 363000 , China.
  • Chen S; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry, Chemical Engineering, and Environment , Minnan Normal University , Zhangzhou 363000 , China.
  • Chen H; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry, Chemical Engineering, and Environment , Minnan Normal University , Zhangzhou 363000 , China.
  • Huang M; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry, Chemical Engineering, and Environment , Minnan Normal University , Zhangzhou 363000 , China.
  • Cai S; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry, Chemical Engineering, and Environment , Minnan Normal University , Zhangzhou 363000 , China.
Org Lett ; 21(24): 9929-9933, 2019 Dec 20.
Article en En | MEDLINE | ID: mdl-31808698
ABSTRACT
A practical and direct method for oxidative cross-coupling of alkenes with dialkylformamides is established employing visible-light-enabled photoredox catalysis. This strategy allows efficient access to diverse unsaturated amides under mild reaction conditions. The application of an appropriate diaryliodonium salt was demonstrated to be critical to the success of this process. This catalyst system is well tolerant of a variety of useful functional groups.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2019 Tipo del documento: Article País de afiliación: China

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2019 Tipo del documento: Article País de afiliación: China
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