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Transition-Metal-Catalyzed Regioselective Functionalization of Monophosphino-o-Carboranes.
Zhang, Zi-Yang; Zhang, Xuepeng; Yuan, Jia; Yue, Chang-Duo; Meng, Sixuan; Chen, Jian; Yu, Guang-Ao; Che, Chi-Ming.
Afiliación
  • Zhang ZY; Department Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, Chemical Biology Center, College of Chemistry, Central China Normal University, Wuhan, 430079, P. R. China.
  • Zhang X; Laboratory of Computational and Drug Design, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School, Shenzhen, 518055, P. R. China.
  • Yuan J; School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an, 710119, P. R. China.
  • Yue CD; Department Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, Chemical Biology Center, College of Chemistry, Central China Normal University, Wuhan, 430079, P. R. China.
  • Meng S; Department Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, Chemical Biology Center, College of Chemistry, Central China Normal University, Wuhan, 430079, P. R. China.
  • Chen J; Department Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, Chemical Biology Center, College of Chemistry, Central China Normal University, Wuhan, 430079, P. R. China.
  • Yu GA; Department Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, Chemical Biology Center, College of Chemistry, Central China Normal University, Wuhan, 430079, P. R. China.
  • Che CM; Department Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, Chemical Biology Center, College of Chemistry, Central China Normal University, Wuhan, 430079, P. R. China.
Chemistry ; 26(22): 5037-5050, 2020 Apr 16.
Article en En | MEDLINE | ID: mdl-32022324
ABSTRACT
A facile approach to the synthesis of diaryl- and dialkyl-substituted monophosphino-o-carboranes by rhodium(I)-catalyzed phosphine-directed B3,6 -H activation has been developed for the first time. Upon switching rhodium(I) to palladium(II), C-arylated and B6 -halogenated products were obtained by using tBuOLi and Li2 CO3 as base, respectively. These discoveries provide some simple and efficient approaches to the modification of monophosphino-o-carboranes.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article