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Control of microenvironment around enzymes by hydrogels.
Kobayashi, Yuichiro; Kohara, Kenji; Kiuchi, Yusuke; Onoda, Hiroki; Shoji, Osami; Yamaguchi, Hiroyasu.
Afiliación
  • Kobayashi Y; Department of Macromolecular Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan. hiroyasu@chem.sci.osaka-u.ac.jp.
  • Kohara K; Department of Macromolecular Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan. hiroyasu@chem.sci.osaka-u.ac.jp.
  • Kiuchi Y; Department of Macromolecular Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan. hiroyasu@chem.sci.osaka-u.ac.jp.
  • Onoda H; Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-0802, Japan. shoji.osami@a.mbox.nagoya-u.ac.jp.
  • Shoji O; Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-0802, Japan. shoji.osami@a.mbox.nagoya-u.ac.jp.
  • Yamaguchi H; Department of Macromolecular Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan. hiroyasu@chem.sci.osaka-u.ac.jp.
Chem Commun (Camb) ; 56(49): 6723-6726, 2020 Jun 18.
Article en En | MEDLINE | ID: mdl-32421111
ABSTRACT
We prepared enzyme-immobilized hydrogels and investigated the effects of the cross-linking density and polymer properties on their oxidation reaction rate. The oxidation rate of enzyme-immobilized hydrogels increased as the cross-linking density in the hydrogels increased. In addition, we controlled the oxidation rate using hydrogels exhibiting an appropriate interaction with a decoy molecule in the hydrogel.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polímeros / Hidrogeles / Reactivos de Enlaces Cruzados / Sistema Enzimático del Citocromo P-450 Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article País de afiliación: Japón
Texto completo
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XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polímeros / Hidrogeles / Reactivos de Enlaces Cruzados / Sistema Enzimático del Citocromo P-450 Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article País de afiliación: Japón