Thioallenoates in Catalytic Enantioselective [2+2]-Cycloadditions with Unactivated Alkenes.

Conner, Michael L; Wiest, Johannes M; Brown, M Kevin

Conner, Michael L; Wiest, Johannes M; Brown, M Kevin.

Afiliación

Conner ML; Indiana University, Department of Chemistry, 800 E. Kirkwood Ave. Bloomington, IN 47405.
Wiest JM; Indiana University, Department of Chemistry, 800 E. Kirkwood Ave. Bloomington, IN 47405.
Brown MK; Indiana University, Department of Chemistry, 800 E. Kirkwood Ave. Bloomington, IN 47405.

Tetrahedron ; 75(24): 3265-3271, 2019 Jun 14.

Article en En | MEDLINE | ID: mdl-33100416

RESUMEN

The application of thioallenoates to catalytic enantioselective [2+2]-cycloadditions with unactivated alkenes is reported.In many cases, the thioallenoates examined exhibit superior reactivity and selectivity compared to the alkoxy analogs generally used in these cycloadditions.

Palabras clave

Allenes; Cycloaddition; Cyclobutane; Enantioselective; Lewis-Acid

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Tetrahedron Año: 2019 Tipo del documento: Article