Treatment of iodine-containing water by the UV/NH2Cl process: Dissolved organic matters transformation, iodinated trihalomethane formation and toxicity variation.
Water Res
; 200: 117256, 2021 Jul 15.
Article
en En
| MEDLINE
| ID: mdl-34062404
ABSTRACT
UV/NH2Cl process is becoming increasingly important for water treatment, while its impact on iodine-containing water remains unknown. In this study, the structure transformation of dissolved organic matters (DOMs), generation of iodinated trihalomethanes (I-THMs), and variation of acute toxicity were evaulated during the UV/NH2Cl treatment of iodine-containing water. The combination of exciation emission matrix-parallel factor analysis and two-dimensional correlation spectroscopy integrated with synchronous fluorescence and infrared absorption spectroscopy showed that fulvic-like fraction of DOM was more susceptible to UV/NH2Cl process and particularly iodo and polysaccharide groups gave the fastest resopnses. Consequently, UV fluence lower than 60 mJ/cm2 promoted the production of I-THMs, while excessive UV exhausted NH2Cl and reactive iodine species and subsequently reduced I-THM generation. Moreover, DOM concentration and source, NH2Cl dosage, and I- concentration had significant impacts on I-THM formation in the UV/NH2Cl process. Additionally, a positive correlation was found between acute toxicity variation and I-THM formation when treating iodine-containing waters with UV/NH2Cl. These results together provide a comprehensive understanding on UV/NH2Cl treatment of iodine-containing water.
Palabras clave
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Contexto en salud:
2_ODS3
Problema de salud:
2_quimicos_contaminacion
Asunto principal:
Contaminantes Químicos del Agua
/
Purificación del Agua
/
Yodo
Idioma:
En
Revista:
Water Res
Año:
2021
Tipo del documento:
Article
País de afiliación:
China