Spatially Separated Superconductivity and Enhanced Charge-Density-Wave Ordering in an IrTe2 Nanoflake.

ABSTRACT

The interplay among collective electronic states like superconductivity (SC) and charge density wave (CDW) is of significance in transition metal dichalcogenides. To date, a consensus on the relationship between SC and CDW has not been established in IrTe2. Here we use the Au-assisted exfoliation method to cleave IrTe2 down to 10 nm. A striking feature is the concurrence of phase separation in a single piece of nanoflake, i.e., the superconducting (P3̅m1) and CDW (P3̅) phases. In the former area, the dimensional fluctuations suppress the CDW ordering and induce SC at 3.5 K. The CDW area at the phase boundary shows enhanced TCDW at 605 K (TCDW = 280 K in the bulk phase), which is accompanied by a unique wrinkle. Detailed analyses suggest that the strain-induced bond breaking of Te-Te dimers favors the CDW. Our works provide compelling evidence of competition between SC and CDW in IrTe2.