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Effect of Temperature and Pressure on Structural and Optical Properties of Organic-Inorganic Hybrid Manganese Halides.
Chen, Yi-Shin; Bao, Zhen; Huang, Wen-Tse; Lazarowska, Agata; Majewska, Natalia; Mahlik, Sebastian; Leniec, Grzegorz; Kaczmarek, Slawomir M; Huang, Hsiao-Yu; Wu, Chun-I; Huang, Di-Jing; Liu, Ru-Shi.
Afiliación
  • Chen YS; Department of Chemistry, National Taiwan University, Taipei 106, Taiwan.
  • Bao Z; Department of Chemistry, National Taiwan University, Taipei 106, Taiwan.
  • Huang WT; Department of Chemistry, National Taiwan University, Taipei 106, Taiwan.
  • Lazarowska A; Institute of Experimental Physics, Faculty of Mathematics, Physics and Informatics, University of Gdansk, Wita Stwosza 57, 80-308 Gdansk, Poland.
  • Majewska N; Institute of Experimental Physics, Faculty of Mathematics, Physics and Informatics, University of Gdansk, Wita Stwosza 57, 80-308 Gdansk, Poland.
  • Mahlik S; Institute of Experimental Physics, Faculty of Mathematics, Physics and Informatics, University of Gdansk, Wita Stwosza 57, 80-308 Gdansk, Poland.
  • Leniec G; Graduate School of Human and Environmental Studies, Kyoto University, Kyoto 606-8501, Japan.
  • Kaczmarek SM; Department of Technical Physics, Faculty of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology in Szczecin, al. Piastow 48, 70-311 Szczecin, Poland.
  • Huang HY; Department of Technical Physics, Faculty of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology in Szczecin, al. Piastow 48, 70-311 Szczecin, Poland.
  • Wu CI; National Synchrotron Radiation Research Center, Hsinchu 300, Taiwan.
  • Huang DJ; Graduate Program in Science and Technology of Synchrotron Light Source, National Tsing Hua University, Hsinchu 300, Taiwan.
  • Liu RS; National Synchrotron Radiation Research Center, Hsinchu 300, Taiwan.
Inorg Chem ; 61(5): 2595-2602, 2022 Feb 07.
Article en En | MEDLINE | ID: mdl-35061382
ABSTRACT
Organic-inorganic hybrid metal halides have recently attracted attention in the global research field for their bright light emission, tunable photoluminescence wavelength, and convenient synthesis method. This study reports the detailed properties of (C10H16N)2MnBr4, which emits bright green light with a high photoluminescence quantum yield. Results of powder X-ray diffraction, photoluminescence, thermogravimetric analysis, and Raman spectra show the phase transition of (C10H16N)2MnBr4 at 430 K. This phase transition was identified as the solid to liquid state of (C10H16N)2MnBr4. Moreover, the pressure- and temperature-induced relationship between structural and optical properties in (C10H16N)2MnBr4 can be identified. This investigation provides deep insights into the luminescent properties of metal halide crystals and promotes further research.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2022 Tipo del documento: Article País de afiliación: Taiwán

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2022 Tipo del documento: Article País de afiliación: Taiwán
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