Effect of Temperature and Pressure on Structural and Optical Properties of Organic-Inorganic Hybrid Manganese Halides.
Inorg Chem
; 61(5): 2595-2602, 2022 Feb 07.
Article
en En
| MEDLINE
| ID: mdl-35061382
ABSTRACT
Organic-inorganic hybrid metal halides have recently attracted attention in the global research field for their bright light emission, tunable photoluminescence wavelength, and convenient synthesis method. This study reports the detailed properties of (C10H16N)2MnBr4, which emits bright green light with a high photoluminescence quantum yield. Results of powder X-ray diffraction, photoluminescence, thermogravimetric analysis, and Raman spectra show the phase transition of (C10H16N)2MnBr4 at 430 K. This phase transition was identified as the solid to liquid state of (C10H16N)2MnBr4. Moreover, the pressure- and temperature-induced relationship between structural and optical properties in (C10H16N)2MnBr4 can be identified. This investigation provides deep insights into the luminescent properties of metal halide crystals and promotes further research.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Año:
2022
Tipo del documento:
Article
País de afiliación:
Taiwán