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Crystal structure and Hirshfeld surface analysis of 6,6'-((1E,1'E)-{[1,4-phenyl-enebis(methyl-ene)]bis(aza-nylyl-idene)}bis-(methane-ylyl-idene))bis-(2-meth-oxy-phenol).
Kansiz, Sevgi; Yesilbag, Semanur; Dege, Necmi; Saif, Eiad; Agar, Erbil.
Afiliación
  • Kansiz S; Samsun University, Faculty of Engineering, Department of Fundamental Sciences, 55420, Samsun, Turkey.
  • Yesilbag S; Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139, Samsun, Turkey.
  • Dege N; Ondokuz Mayis University, Faculty of Arts and Sciences, Department of Physics, 55139, Samsun, Turkey.
  • Saif E; Department of Computer and Electronic Engineering Technology, Sanaa Community, College, Sanaa, Yemen.
  • Agar E; Ondokuz Mayis University, Faculty of Engineering, Department of Electrical and Electronic Engineering, 55139, Samsun, Turkey.
Acta Crystallogr E Crystallogr Commun ; 78(Pt 1): 84-87, 2022 Jan 01.
Article en En | MEDLINE | ID: mdl-35079431
The Schiff base compound, C24H24N2O4, was synthesized by the inter-action of 2-hy-droxy-3-meth-oxy benzaldehyde and 1,4-benzene dimethanamine in ethanol, and crystallizes in the monoclinic space group P21/n with Z' = 0.5. The mol-ecule is not planar, the 1,4-di-ethyl-benzene and the phenol rings are twisted with respect to each other, making a dihedral angle of 74.27 (5)°. The mol-ecular structure is stabilized by an O-H⋯N hydrogen bond, forming an S(6) ring motif. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, resulting in the formation of sheets parallel to the bc plane. A Hirshfeld surface analysis was undertaken to investigate the various inter-molecular contacts controlling the supra-molecular topology, suggesting the H⋯O (18%) contacts to be the most significant inter-actions, whereas the H⋯H (50.5%) and C⋯H (24.3%) inter-actions are less significant.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr E Crystallogr Commun Año: 2022 Tipo del documento: Article País de afiliación: Turquía

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr E Crystallogr Commun Año: 2022 Tipo del documento: Article País de afiliación: Turquía
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