Tailoring Single-Atom Platinum for Selective and Stable Catalysts in Propane Dehydrogenation.
Chempluschem
; 87(4): e202100560, 2022 Feb 14.
Article
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| MEDLINE
| ID: mdl-35194957
ABSTRACT
Propane dehydrogenation has been a promising method for producing propylene that has the potentials to meet the increasing global demand for propylene. However, owing to the restricted equilibrium conversion caused by the high endothermicity, even the Pt-based catalysts, which exhibit high activity and selectivity, severely suffer significantly from coke formation and/or nanoparticle sintering at realistic reaction temperatures, resulting in a short catalyst lifetime. As a result, few innovative catalysts in terms of catalytic activity, selectivity, and stability, have been produced. In this Review, we focus on the characteristics of single-atom-like Pt sites for PDH and attempt to provide suggestions for developing highly efficient catalysts. First, we briefly describe the fundamental strategies. Following that, the remarkable catalysis is addressed by three different distinct sorts of state-of-the-art single-atom-like Pt catalysts are discussed. Additionally, we present other promising catalyst design approaches that are not based on single-atom-like Pt catalysts, as well as future research challenges in this field.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chempluschem
Año:
2022
Tipo del documento:
Article
País de afiliación:
Japón