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Copper(II)-photocatalyzed decarboxylative oxygenation of carboxylic acids.
Reichle, Alexander; Sterzel, Hannes; Kreitmeier, Peter; Fayad, Remi; Castellano, Felix N; Rehbein, Julia; Reiser, Oliver.
Afiliación
  • Reichle A; Institute of Organic Chemistry, University of Regensburg, Universitätsstr. 31, 93053 Regensburg, Germany. oliver.reiser@chemie.uni-regensburg.de.
  • Sterzel H; Institute of Organic Chemistry, University of Regensburg, Universitätsstr. 31, 93053 Regensburg, Germany. oliver.reiser@chemie.uni-regensburg.de.
  • Kreitmeier P; Institute of Organic Chemistry, University of Regensburg, Universitätsstr. 31, 93053 Regensburg, Germany. oliver.reiser@chemie.uni-regensburg.de.
  • Fayad R; Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA.
  • Castellano FN; Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA.
  • Rehbein J; Institute of Organic Chemistry, University of Regensburg, Universitätsstr. 31, 93053 Regensburg, Germany. oliver.reiser@chemie.uni-regensburg.de.
  • Reiser O; Institute of Organic Chemistry, University of Regensburg, Universitätsstr. 31, 93053 Regensburg, Germany. oliver.reiser@chemie.uni-regensburg.de.
Chem Commun (Camb) ; 58(28): 4456-4459, 2022 Apr 05.
Article en En | MEDLINE | ID: mdl-35201250
Showcasing the concept of light-induced homolysis for the generation of radicals, the CuII-photocatalyzed decarboxylative oxygenation of carboxylic acids with molecular oxygen as the terminal oxidant is described. Two CuII-carboxylate complexes with different coordination geometries were synthesized and characterized by X-ray analysis, correlating their structure with their ability to initiate light-induced decarboxylations.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Ácidos Carboxílicos / Cobre Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: Alemania
Texto completo
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Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Ácidos Carboxílicos / Cobre Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: Alemania