The versatility of nanocellulose, modification strategies, and its current progress in wastewater treatment and environmental remediation.

ABSTRACT

Deterioration in the environmental ecosystems through the depletion of nonrenewable resources and the burden of deleterious contaminants is considered a global concern. To this end, great interest has been shown in the use of renewable and environmentally-friendly reactive materials dually to promote environmental sustainability and cope with harmful contaminants. Among the different available options, the use of nanocellulose (NC) as an environmentally benign and renewable natural nanomaterial is an attractive candidate for environmental remediation owing to its miraculous physicochemical characteristics. This review discusses the intrinsic properties and the structural aspects of different types of NC, including cellulose nanofibrils (CNFs), cellulose nanocrystals (CNCs), and bacterial cellulose (BC) or bacterial nanocellulose (BNC). Also, the different modification strategies involving the functionalization or hybridization of NC by using different functional and reactive materials aimed at wastewater remediation have been elaborated. The modified or hybridized NC has been explored for its applications in the removal or degradation of aquatic contaminants through adsorption, filtration, coagulation, catalysis, photocatalysis, and pollutant sensing. This review highlights the role of NC in the modified composites and describes the underlying mechanisms involved in the removal of contaminants. The life-cycle assessment (LCA) of NC is discussed to unveil the hidden risks associated with its production to the final disposal. Moreover, the contribution of NC in the promotion of waste management at different stages has been described in the form of the five-Rs strategy. In summary, this review provides rational insights to develop NC-based environmentally-friendly reactive materials for the removal and degradation of hazardous aquatic contaminants.