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Blue Emission of Tetrafluorobenzocarbazole Under the Interactions of Nitrogen-oxygen Saturated hydrogen Bonds with Aggregated Proton Acid.
Hu, Kaibo; Lian, Guangchang; Zhou, Meng; Liu, Ying; Lu, Chichong; Jin, Guofan.
Afiliación
  • Hu K; School of Pharmacy, Jiangsu University, Zhenjiang, 212013, China.
  • Lian G; School of Pharmacy, Jiangsu University, Zhenjiang, 212013, China.
  • Zhou M; School of Pharmacy, Jiangsu University, Zhenjiang, 212013, China.
  • Liu Y; School of Pharmacy, Jiangsu University, Zhenjiang, 212013, China.
  • Lu C; College of Chemistry and Materials Engineering, Beijing Technology and Business University, Beijing, 100048, People's Republic of China.
  • Jin G; School of Pharmacy, Jiangsu University, Zhenjiang, 212013, China. organicboron@ujs.edu.cn.
J Fluoresc ; 33(3): 895-910, 2023 May.
Article en En | MEDLINE | ID: mdl-36520363
Two novel tetrafluorobenzocarbazole and containing the amino branch introduced at the end of the molecule are synthesized by a simple method. The tetrafluorobenzocarbazole as the electron donor with electron-rich fluoride ions connected by π-benzyl ring conjugation structure, which affects the overall electron cloud density. Moreover, the amino branch introduced at the end of the molecule, which makes it easy to form intermolecular hydrogen bonds and affected photophysical properties. Meanwhile, the photophysical property of both compounds are discussed under different acidic conditions. The UV-absorption show that around ~286 nm is mainly attributed to the strong structural absorption band peak of the π-π ∗ transition of the carbazole moiety, and the irregular absorption band around ~314 nm and ~326 nm are mainly attributed to the n-π ∗ transition of the carbazole group conjugate with the adjacent molecule. The emission spectrum of both compounds showed that the intensity of fluorescence decreased in different degrees after the addition of the acidic solution. Furthermore, the electrochemical properties were evidenced by cyclic voltammetry (CV) and density functional theory (DFT) calculations, and the orbital conformation (HOMOs-LUMOs) was simulated by Gaussian 09 software and its crystal structure was observed by X-ray diffraction (XRD). The results exhibited that both compounds are electrochemically stable blue small-molecule fluorescent substances, and expected that both compounds can be novel and stable acid-sensitive organic blue-light materials.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Fluoresc Asunto de la revista: BIOFISICA Año: 2023 Tipo del documento: Article País de afiliación: China

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Fluoresc Asunto de la revista: BIOFISICA Año: 2023 Tipo del documento: Article País de afiliación: China
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