Veil of the Charge Transfer State in Bay-Annulated Indigo-Based Donor-Acceptor Systems: Charge Separation versus Singlet Fission.

ABSTRACT

Bay-annulated indigo (BAI) is a new potential SF-active building block, which has aroused great interest in the design of highly stable singlet fission materials. However, singlet fission of unfunctionalized BAI is inactive due to the inappropriate energy levels. Herein, we seek to develop a new design strategy by introducing the charge transfer interaction to tune the exciton dynamics of BAI derivatives. A new donor-acceptor molecule (TPA-2BAI) and two control molecules (TPA-BAI and 2TPA-BAI) were designed and synthesized to unravel the veil of CT states in tuning the excited-state dynamics of BAI derivatives. Transient absorption spectroscopy studies show that CT states are generated immediately following the excitation. However, the low-lying CT states induced by strong donor-acceptor interactions result in them acting as trap states and inhibiting the SF process. These results show that the low-lying CT state is detrimental to SF and provide insight into the design of CT-mediated BAI-based SF materials.