Towards a scalable and controllable preparation of highly-uniform surface-enhanced Raman scattering substrates: Defect-free nanofilms as templates.
J Colloid Interface Sci
; 647: 23-31, 2023 Oct.
Article
en En
| MEDLINE
| ID: mdl-37244173
ABSTRACT
The uniformity and reproducibility of substrates highly determine the applicability of surface-enhanced Raman scattering (SERS). Production of them, however, remains a challenge. Herein, we report a template-based strategy for the strictly controllable and handily scalable preparation of a very uniform SERS substrate, Ag nanoparticles (AgNPs)/nanofilm, where the template used is a flexible, transparent, self-standing, defect-free and robust nanofilm. Importantly, the obtained AgNPs/nanofilm is self-adhesive to surfaces of different properties and morphologies, ensuring in-situ and at real-time SERS detection. The enhancement factor (EF) of the substrate for rhodamine 6G (R6G) could reach 5.8 × 1010 with a detection limit (DL) of 1.0 × 10-15 mol L-1. Moreover, 500 bending tests and one-month storage showed no observable performance degradation, and up to 50.0 cm2 scaled-up preparation depicted negligible effect upon the structure and the sensing performance. The real-life applicability of AgNPs/nanofilm was demonstrated by the sensitive detection of tetramethylthiuram disulfide on cherry tomato and fentanyl in methanol with a routine handheld Raman spectrometer. This work thus provides a reliable strategy for large area wet-chemical preparation of high-quality SERS substrates.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
J Colloid Interface Sci
Año:
2023
Tipo del documento:
Article
País de afiliación:
China