Scalable Production of Catecholamine-Densified MXene Coatings for Electromagnetic Shielding and Infrared Stealth.
Small
; 19(46): e2304278, 2023 Nov.
Article
en En
| MEDLINE
| ID: mdl-37431209
ABSTRACT
Processing transition metal carbides/nitrides (MXenes) inks into large-area functional coatings expects promising potential for electromagnetic interference (EMI) shielding and infrared stealth. However, the coating performances, especially for scalable fabrication techniques, are greatly constrained by the flake size and stacking manner of MXene. Herein, the large-area production of highly densified and oriented MXene coatings is demonstrated by engineering interfacial interactions of small MXene flakes with catecholamine molecules. The catecholamine molecules can micro-crosslink MXene nanosheets, significantly improving the ink's rheological properties. It favors the shear-induced sheet arrangement and inhibition of structural defects in the blade coating process, making it possible to achieve high orientation and densification of MXene assembly by either large-area coating or patterned printing. Interestingly, the MXene/catecholamine coating exhibits high conductivity of up to 12â¯247 S cm-1 and ultrahigh specific EMI shielding effectiveness of 2.0 ×10 5 dB cm2 g-1 , obviously superior to most of the reported MXene materials. Furthermore, the regularly assembled structure also endows the MXene coatings with low infrared emissivities for infrared stealth applications. Therefore, MXene/catecholamine coatings with ultraefficient EMI shielding and low infrared emissivity prove the feasibility of applications in aerospace, military, and wearable devices.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Small
Asunto de la revista:
ENGENHARIA BIOMEDICA
Año:
2023
Tipo del documento:
Article
País de afiliación:
China