A dual-cycle regeneration to recover high-value and high-purity FePO4 from real wastewater for Li-battery application.
Water Res
; 242: 120300, 2023 Aug 15.
Article
en En
| MEDLINE
| ID: mdl-37441872
ABSTRACT
The recovery of high-purity and high-value FePO4 raw materials from wastewater has great prospects in LiFePO4 battery industry due to the huge demand for new energy vehicle. However, the conventional in-situ FePO4 precipitation, as well as ex-situ PO43- adsorption-alkali regeneration, was incapable of efficiently obtaining high-purity products. To solve these problems, a dual-cycle regeneration method of Fe-NH2-polyacrylonitrile (PAN) adsorbent and H2SO4 desorbing solution was proposed to ex-situ FePO4 recovery from wastewater for Li-battery application. Benefitted from coordination interaction and electrostatic attraction, the maximum PO43- adsorption capacity of Fe-NH2-PAN reached 73.1 ± 0.4 mg/g. The average PO43- removal rate of continuous flow devices were 88.5% and 91.3% when treating low-P-concentration (0.22 mg/L) municipal wastewater (MW) and high-P-concentration (48.9 mg/L) slaughterhouse wastewater (SW) respectively. Furthermore, high-purity FePO4 analyzed by XRD spectra was achieved from the desorption solution at pH â¼1.6, resulting in the ultrahigh P recovery efficiencies of 91.4 ± 3.2%-96.3 ± 2.5% for SW and 82.7 ± 3.5% for MW. Besides, the LiFePO4/C electrodes made of recycled FePO4 exhibited a better discharge capacity (37.3 - 55.8 mAh/g) than that of commercial FePO4 agent (32.2 - 35.1 mAh/g) from 80 to 132 cycles, which showed the promising feasibility of recovering FePO4 from wastewater for Li-battery application.
Palabras clave
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Fosfatos
/
Aguas Residuales
Idioma:
En
Revista:
Water Res
Año:
2023
Tipo del documento:
Article
País de afiliación:
China