Asterarcys quadricellulare algae-mediated copper oxide nanoparticles as a robust and recyclable catalyst for the degradation of noxious dyes from wastewater.

ABSTRACT

The present article explores the synthesis of copper oxide nanoparticles (CuO NPs) utilizing Asterarcys quadricellulare algal extract and examines the effect of various reaction parameters on the size and morphology of the nanoparticles. The samples were thoroughly characterized using XRD, FTIR, UV-vis, FE-SEM, and EDS techniques. The XRD analysis disclosed that the size of the synthesized nanoparticles could be controlled by adjusting the reaction parameters, ranging from 4.76 nm to 13.70 nm along the highest intensity plane (111). FTIR spectroscopy provided evidence that the phytochemicals are present in the algal extract. We have compared the photocatalytic activity of biologically and chemically synthesized CuO NPs and observed that biologically synthesized CuO NPs showed better photocatalytic activity than chemically synthesized CuO NPs. The biosynthesized CuO NPs (S8) demonstrated outstanding photodegradation activity towards four different organic dyes, namely BBY, BG, EBT, and MG, with degradation percentages of 95.78%, 98.02%, 94.15%, and 96.04%, respectively. The maximum degradation efficacy of 98.02% was observed for the BG dye at optimized reaction conditions and 60 min of visible light exposure. The kinetics of the photodegradation reaction followed the pseudo-first-order kinetic model, and the rate constant (k) was calculated using the Langmuir-Hinshelwood model for each dye. This study provides an efficient and sustainable approach for synthesizing CuO NPs with superior photocatalytic degradation efficiency towards organic dyes.