A heteropolytungstate based 2D layered porous framework with high proton conductivity.

Yang, Mengnan; Zhang, Yao; Ji, Shiyan; Li, Huafeng; Ma, Xinyi; Jin, Yuzhen; Ma, Pengtao; Wang, Jingping; Niu, Jingyang

Yang, Mengnan; Zhang, Yao; Ji, Shiyan; Li, Huafeng; Ma, Xinyi; Jin, Yuzhen; Ma, Pengtao; Wang, Jingping; Niu, Jingyang.

Afiliación

Yang M; Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China. jyniu@henu.edu.cn.
Zhang Y; Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China. jyniu@henu.edu.cn.
Ji S; Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China. jyniu@henu.edu.cn.
Li H; Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China. jyniu@henu.edu.cn.
Ma X; Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China. jyniu@henu.edu.cn.
Jin Y; Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China. jyniu@henu.edu.cn.
Ma P; Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China. jyniu@henu.edu.cn.
Wang J; Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China. jyniu@henu.edu.cn.
Niu J; Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China. jyniu@henu.edu.cn.

Chem Commun (Camb) ; 59(91): 13627-13630, 2023 Nov 14.

Article en En | MEDLINE | ID: mdl-37902595

ABSTRACT

ABSTRACT

A heteropolytungstate cluster [{Ru2O(bpy)2}2{Bi2W32O110}]10- (bpy = C10H8N2) was incorporated into a 2 1 type layered porous framework by interweaving the Na+ bridged cluster chains through the hydrogen bonding ability of the bpy ligands. It features multiple pore channels rich in hydrogen-bond network, contributing high conductivities > 10-2 S cm-1 at 298-358 K and 85% RH.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article

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