Rapid assembly of structurally diverse cyanamides and disulfanes <i>via</i> base-mediated aminoalkylation of aryl thiourea.

Zheng, Yongpeng; Li, Jianxiao; Qi, Chaorong; Wu, Wanqing; Jiang, Huanfeng

Rapid assembly of structurally diverse cyanamides and disulfanes via base-mediated aminoalkylation of aryl thiourea.

Zheng, Yongpeng; Li, Jianxiao; Qi, Chaorong; Wu, Wanqing; Jiang, Huanfeng.

Afiliación

Zheng Y; Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology Guangzhou 510640 P. R. China jianghf@scut.edu.cn.
Li J; Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology Guangzhou 510640 P. R. China jianghf@scut.edu.cn.
Qi C; Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology Guangzhou 510640 P. R. China jianghf@scut.edu.cn.
Wu W; Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology Guangzhou 510640 P. R. China jianghf@scut.edu.cn.
Jiang H; Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology Guangzhou 510640 P. R. China jianghf@scut.edu.cn.

RSC Adv ; 13(47): 33047-33052, 2023 Nov 07.

Article en En | MEDLINE | ID: mdl-37954416

ABSTRACT

ABSTRACT

A general method for the preparation of cyanamides and disulfanes from aryl thiourea and halide through a base-mediated strategy is described. Mercaptan and N-aryl cyanamide are the key intermediates in the reaction. The current method is convenient, eco-friendly, and has high yields for the synthesis of substituted cyanamide and functional disulfanes in a one-pot procedure from readily available starting materials.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: RSC Adv Año: 2023 Tipo del documento: Article