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Visible-Light-Enabled Catalytic Approach to N,O-Spirocycles through Amidyl Radical Addition/Cyclization.
Liang, Zhihui; Yu, Yushen; Zhang, Lele; Xue, Guotao; Liu, Min; Zhang, Yirui; Huang, Mingqiang; Cai, Lina; Cai, Shunyou.
Afiliación
  • Liang Z; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry Chemical Engineering, and Environment, Minnan Normal University, Zhangzhou 363000, China.
  • Yu Y; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry Chemical Engineering, and Environment, Minnan Normal University, Zhangzhou 363000, China.
  • Zhang L; Key Laboratory of Chemical Genomics of Guangdong Province, School of Chemical Biology and Biotechnology, Shenzhen Graduate School, Peking University, Shenzhen 518055, China.
  • Xue G; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry Chemical Engineering, and Environment, Minnan Normal University, Zhangzhou 363000, China.
  • Liu M; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry Chemical Engineering, and Environment, Minnan Normal University, Zhangzhou 363000, China.
  • Zhang Y; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry Chemical Engineering, and Environment, Minnan Normal University, Zhangzhou 363000, China.
  • Huang M; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry Chemical Engineering, and Environment, Minnan Normal University, Zhangzhou 363000, China.
  • Cai L; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry Chemical Engineering, and Environment, Minnan Normal University, Zhangzhou 363000, China.
  • Cai S; Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry Chemical Engineering, and Environment, Minnan Normal University, Zhangzhou 363000, China.
Org Lett ; 26(1): 298-303, 2024 Jan 12.
Article en En | MEDLINE | ID: mdl-38153355
ABSTRACT
A rational combination of photoredox catalyst anthraquinone and hydrogen atom transfer (HAT) catalyst methyl thioglycolate allows for the rapid and straightforward conversion of a range of 2-amidated acetylenic alcohols to multifunctional N,O-spirocycles under visible light irradiation. With oxygen as the sole terminal oxidant, these reactions can be carried out efficiently at room temperature without the involvement of transition metals or strong oxidants. The successful application of this mild catalytic strategy in the late-stage functionalization of bioactive skeletons further highlights its practical value.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China