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Influence of Nano-CeO2 and Graphene Nanoplatelets on the Conductivity and Dielectric Properties of Poly(vinylidene fluoride) Nanocomposite Films.
Pandey, Mayank; Deshmukh, Kalim; Dhandapani, Karthik; Singh, Ram Sevak.
Afiliación
  • Pandey M; Department of Physics and Electronics, Kristu Jayanti College (Autonomous), Bangalore 560077, India.
  • Deshmukh K; New Technologies - Research Center, University of West Bohemia, Plzen̆ 30100, Czech Republic.
  • Dhandapani K; Department of Physics, School of Engineering, Presidency University, Bangalore 560064, India.
  • Singh RS; Department of Physics, OP Jindal University, Raigarh, Chhattisgarh 496109, India.
Langmuir ; 40(3): 1909-1921, 2024 Jan 23.
Article en En | MEDLINE | ID: mdl-38197127
ABSTRACT
Novel three-phase polymer nanocomposites (PNCs) based on cerium oxide (CeO2) nanoparticles (NPs) and graphene nanoplatelets (GNPs) incorporated in a poly(vinylidene fluoride) (PVDF) matrix were formulated using a solution-casting approach. To understand the structural and morphological features of PVDF/CeO2/GNP nanocomposites (NCs), scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) analyses were accomplished. The PVDF/CeO2/GNP NCs displayed improved thermal stability which resulted from strong bonding between GNPs and CeO2 NPs and restriction of the polymer chain movement. The introduction of CeO2 NPs and GNPs within the PVDF matrix and good synergy between CeO2 NPs and GNPs led to variable mechanical properties of the prepared NCs. The PVDF/CeO2/GNP NCs portrayed reduced thermal stability, which could be due to the increased mobility of PVDF chains imposed by GNPs leading to the formation of volatile degradation products. Moreover, PVDF/CeO2/GNP NCs exhibited good electrical conductivity and high dielectric permittivity. The obtained dielectric permittivity value for the PVDF/CeO2/GNP NCs was 3-fold greater than PVDF/CeO2 NCs, making these novel tertiary composite materials a probable candidate for energy-storage applications.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Langmuir Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: India

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Langmuir Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: India
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