Green-Emitting Extended B3,N2-Doped Polycyclic Aromatic Hydrocarbon with Multiple Resonance Structure.
Org Lett
; 26(4): 939-944, 2024 Feb 02.
Article
en En
| MEDLINE
| ID: mdl-38266241
ABSTRACT
An air-stable B3,N2-PAH (B3N2; nine annulated six-membered rings) was synthesized from 1-X-2,6-di(azasilaanthryl)benzenes (X = Cl, I) via lithiation/borylation, electrophilic aromatic borylation, and Si/B exchange. The heteroatom distribution in B3N2 meets the requirements for multiple resonance thermally activated delayed fluorescence (MR-TADF). Indeed, B3N2 emits green light (λem = 523 nm; ΦPL = 85%; CHCl3) with a small fwhm of 0.15 eV. Lifetimes for prompt (7.8 ns) and delayed (60 µs) fluorescence were measured in PMMA.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Org Lett
Asunto de la revista:
BIOQUIMICA
Año:
2024
Tipo del documento:
Article
País de afiliación:
Alemania