A New Life For Nitrile-Butadiene Rubber: Co-Harnessing Metathesis And Condensation For Reincorporation Into Bio-Based Materials.
Angew Chem Int Ed Engl
; 63(12): e202319414, 2024 Mar 18.
Article
en En
| MEDLINE
| ID: mdl-38295149
ABSTRACT
Efficient plastic recycling processes are crucial for the production of value-added products or intermediates. Here, we present a multicatalytic route that allows the degradation of nitrile-butadiene rubber, cross-metathesis of the formed oligomers, and polymerization of the resulting dicarboxylic acids with bio-based diols, providing direct access to unsaturated polyesters. This one-pot approach combines the use of commercially available catalysts that are active and selective under mild conditions to synthesize renewable copolymers without the need to isolate intermediates.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2024
Tipo del documento:
Article
País de afiliación:
Francia