Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies.

Liu, Lei; Pan, Chun-Yang; He, Yong; Zhong, Li-Juan; Beckett, Michael A

Co^(II)-doped hybrid Zn^(II) tetraborate complexes, [Zn_xCo_(1-x)(1,3-dap)B₄O₇] (1,3-dap = 1,3-diaminopropane): BET analysis and N₂/H₂O/D₂O adsorption studies.

Liu, Lei; Pan, Chun-Yang; He, Yong; Zhong, Li-Juan; Beckett, Michael A.

Afiliación

Liu L; School of Light Industry and Chemical Engineering, Guangdong University of Technology, Guangzhou 510006, P.R. China. panchuny@gdut.edu.cn.
Pan CY; School of Light Industry and Chemical Engineering, Guangdong University of Technology, Guangzhou 510006, P.R. China. panchuny@gdut.edu.cn.
He Y; School of Light Industry and Chemical Engineering, Guangdong University of Technology, Guangzhou 510006, P.R. China. panchuny@gdut.edu.cn.
Zhong LJ; School of Light Industry and Chemical Engineering, Guangdong University of Technology, Guangzhou 510006, P.R. China. panchuny@gdut.edu.cn.
Beckett MA; School of Natural Sciences, Bangor University, Gwynedd, LL57 2UW, UK.

Dalton Trans ; 53(10): 4637-4642, 2024 Mar 05.

Article en En | MEDLINE | ID: mdl-38354056

ABSTRACT

ABSTRACT

A series of mono/bimetallic isostructural hybrid tetraborates of the general formula [ZnxCo(1-x)(1,3-dap)B4O7] has been prepared using a solvothermal method. Their adsorption/desorption curves for H2O and D2O demonstrate that these materials have a stronger affinity for H2O than for D2O and enrich the D2O content of D2O/H2O mixtures.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article

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