Sodium hydroxide/magnesium chloride multistage activated sludge biochar: interfacial chemical behavior and Cd(II) adsorption performance.

ABSTRACT

To enhance the adsorption performance of municipal sludge biochar on Cd(II), modified sludge biochar was prepared by sodium hydroxide/magnesium chloride (NaOH/MgCl2) graded activation, and the Cd(II) adsorption performance on sludge biochar (BC), NaOH-activated sludge biochar (NBC) and NaOH/MgCl2 activated sludge biochar (NBC-Mg) was investigated. The results showed that NaOH/MgCl2 graded activation upgraded the surface structure and enhanced the graphitization of sludge biochar. The adsorption experiments indicated that the adsorption kinetic and adsorption isotherm for Cd(II) were in accordance with the pseudo second-order kinetic and Langmuir model. The adsorption capacity of NBC-Mg (143.49 mg/g) for Cd(II) was higher than that of BC (50.40 mg/g) and NBC (85.20 mg/g). The mechanism of Cd(II) adsorption included ion exchange, complexation, cation-π interaction, and mineral precipitation. After five regeneration, the removal efficiency of Cd(II) by NBC-Mg remained above 90%. This work indicated that sludge biochar prepared by multistage activation could be an effective material for Cd-containing wastewater treatment.