A floating biosorbent of polylactide and carboxylated cellulose from biomass for effective removal of methylene blue from water.

ABSTRACT

A floating adsorbent bead was prepared from polylactide (PLA) and maleic anhydride (MAH)-modified cellulose in a one-pot process (OP bead). Cellulose was extracted from waste lemongrass leaf (LGL) and modified with MAH in the presence of dimethylacetamide (DMAc). PLA was then added directly into the system to form sorbent beads by a phase separation process that reused unreacted MAH and DMAc as a pore former and a solvent, respectively. The chemical modification converted cellulose macrofibres (55.1 ± 31.5 µm) to microfibers (8.8 ± 1.5 µm) without the need for grinding. The OP beads exhibited more and larger surface pores and greater thermal stability than beads prepared conventionally. The OP beads also removed methylene blue (MB) more effectively, with a maximum adsorption capacity of 86.19 mg⋅g-1. The adsorption of MB on the OP bead fitted the pseudo-second order and the Langmuir isotherm models. The OP bead was reusable over five adsorption cycles, retaining 88 % of MB adsorption. In a mixed solution of MB and methyl orange (MO), the OP bead adsorbed 96 % of the cationic dye MB while repelling the anionic dye MO. The proposed method not only reduced time, energy and chemical consumption, but also enabled the fabrication of a green, effective and easy-to-use biosorbent.