Your browser doesn't support javascript.
loading
A chiral photoswitch based on enantiospecific interconversion between binaphthyl and helicenoid skeletons.
Nakagawa, Tetsuya; Kato, Ryuji; Iiyoshi, Yuichi; Furuya, Masaki; Kitano, Tomoki; Nakamura, Ryo; Yokoyama, Yasushi; Ubukata, Takashi.
Afiliación
  • Nakagawa T; Department of Chemistry and Life Science, Graduate School of Engineering Science, Yokohama National University, 79-5, Tokiwadai, Hodogaya, Yokohama, Kanagawa 240-8501, Japan. ubukata-takashi-wy@ynu.ac.jp.
  • Kato R; Department of Chemistry and Life Science, Graduate School of Engineering Science, Yokohama National University, 79-5, Tokiwadai, Hodogaya, Yokohama, Kanagawa 240-8501, Japan. ubukata-takashi-wy@ynu.ac.jp.
  • Iiyoshi Y; Department of Chemistry and Life Science, Graduate School of Engineering Science, Yokohama National University, 79-5, Tokiwadai, Hodogaya, Yokohama, Kanagawa 240-8501, Japan. ubukata-takashi-wy@ynu.ac.jp.
  • Furuya M; Department of Chemistry and Life Science, Graduate School of Engineering Science, Yokohama National University, 79-5, Tokiwadai, Hodogaya, Yokohama, Kanagawa 240-8501, Japan. ubukata-takashi-wy@ynu.ac.jp.
  • Kitano T; Department of Chemistry and Life Science, Graduate School of Engineering Science, Yokohama National University, 79-5, Tokiwadai, Hodogaya, Yokohama, Kanagawa 240-8501, Japan. ubukata-takashi-wy@ynu.ac.jp.
  • Nakamura R; Department of Chemistry and Life Science, Graduate School of Engineering Science, Yokohama National University, 79-5, Tokiwadai, Hodogaya, Yokohama, Kanagawa 240-8501, Japan. ubukata-takashi-wy@ynu.ac.jp.
  • Yokoyama Y; Department of Chemistry and Life Science, Graduate School of Engineering Science, Yokohama National University, 79-5, Tokiwadai, Hodogaya, Yokohama, Kanagawa 240-8501, Japan. ubukata-takashi-wy@ynu.ac.jp.
  • Ubukata T; Department of Chemistry and Life Science, Graduate School of Engineering Science, Yokohama National University, 79-5, Tokiwadai, Hodogaya, Yokohama, Kanagawa 240-8501, Japan. ubukata-takashi-wy@ynu.ac.jp.
Chem Commun (Camb) ; 60(39): 5149-5152, 2024 May 09.
Article en En | MEDLINE | ID: mdl-38591265
ABSTRACT
A novel chiral photoswitch composed of a binaphthyl unit and a hexafluorocyclopentene ring has been synthesized. This chiral photoswitch exhibited thermally reversible photochromism between the binaphthyl and helicenoid forms based on 6π-electrocyclization. The helicity of the binaphthyl moiety was reversed upon stereospecific photocyclization and reverted back during the thermal ring opening.
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Japón
Texto completo
Añadir a Mi BVS
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Japón