Chiral Transfer of Linear Polysiloxane with Preferred-Handed Helical Conformation.

Mure, Tomoki; Kinoshita, Yakumo; Sakai, Hinari; Morii, Shunsuke; Wu, Hsin-Ni; Yung, Tsz-Ming; Yu, Hao-Cheng; Nagashima, Kodai; Higashiguchi, Wataru; Ohta, Noboru; Hayakawa, Teruaki; Nakamura, Yoshinobu; Fujii, Syuji; Li, Ming-Chia; Hirai, Tomoyasu

Mure, Tomoki; Kinoshita, Yakumo; Sakai, Hinari; Morii, Shunsuke; Wu, Hsin-Ni; Yung, Tsz-Ming; Yu, Hao-Cheng; Nagashima, Kodai; Higashiguchi, Wataru; Ohta, Noboru; Hayakawa, Teruaki; Nakamura, Yoshinobu; Fujii, Syuji; Li, Ming-Chia; Hirai, Tomoyasu.

Afiliación

Mure T; Department of Applied Chemistry, Faculty of Engineering and Graduate School of Engineering, Osaka Institute of Technology, 5-16-1 Omiya Asahi-ku, Osaka 535-8585, Japan.
Kinoshita Y; Department of Applied Chemistry, Faculty of Engineering and Graduate School of Engineering, Osaka Institute of Technology, 5-16-1 Omiya Asahi-ku, Osaka 535-8585, Japan.
Sakai H; Department of Applied Chemistry, Faculty of Engineering and Graduate School of Engineering, Osaka Institute of Technology, 5-16-1 Omiya Asahi-ku, Osaka 535-8585, Japan.
Morii S; Department of Applied Chemistry, Faculty of Engineering and Graduate School of Engineering, Osaka Institute of Technology, 5-16-1 Omiya Asahi-ku, Osaka 535-8585, Japan.
Wu HN; Department of Biological Science and Technology, Center For Intelligent Drug Systems and Smart Bio-devices (IDS2B), National Yang Ming Chiao Tung University, Hsinchu 30010, Taiwan.
Yung TM; Department of Biological Science and Technology, Center For Intelligent Drug Systems and Smart Bio-devices (IDS2B), National Yang Ming Chiao Tung University, Hsinchu 30010, Taiwan.
Yu HC; Department of Biological Science and Technology, Center For Intelligent Drug Systems and Smart Bio-devices (IDS2B), National Yang Ming Chiao Tung University, Hsinchu 30010, Taiwan.
Nagashima K; Department of Materials Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1-S8-36 Ookayama Meguro-ku, Tokyo 152-8552, Japan.
Higashiguchi W; Department of Materials Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1-S8-36 Ookayama Meguro-ku, Tokyo 152-8552, Japan.
Ohta N; Japan Synchrotron Radiation Research Institute, SPring-8, Sayo, Hyogo 679-5198, Japan.
Hayakawa T; Department of Materials Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1-S8-36 Ookayama Meguro-ku, Tokyo 152-8552, Japan.
Nakamura Y; Department of Applied Chemistry, Faculty of Engineering and Graduate School of Engineering, Osaka Institute of Technology, 5-16-1 Omiya Asahi-ku, Osaka 535-8585, Japan.
Fujii S; Department of Applied Chemistry, Faculty of Engineering and Graduate School of Engineering, Osaka Institute of Technology, 5-16-1 Omiya Asahi-ku, Osaka 535-8585, Japan.
Li MC; Department of Biological Science and Technology, Center For Intelligent Drug Systems and Smart Bio-devices (IDS2B), National Yang Ming Chiao Tung University, Hsinchu 30010, Taiwan.
Hirai T; Department of Applied Chemistry, Faculty of Engineering and Graduate School of Engineering, Osaka Institute of Technology, 5-16-1 Omiya Asahi-ku, Osaka 535-8585, Japan.

ACS Macro Lett ; 13(5): 537-541, 2024 May 21.

Article en En | MEDLINE | ID: mdl-38629809

ABSTRACT

ABSTRACT

We report the preparation of chiral silica using a linear polysiloxane main chain with a preferred-handed helical structure as the template. Poly(methylvinyl siloxane) (PMVS) with a cysteine derivative side chain designated as PMVS-Cys was prepared using anionic polymerization and an ene-thiol reaction. PMVS-Cys forms a helical conformation in both solution and film via hydrogen bonding between amide groups at side chains. The helical structure remains during the calcination process, resulting in silica with helical structure. The silica with a helical structure shows optical activity.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: ACS Macro Lett Año: 2024 Tipo del documento: Article País de afiliación: Japón

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