Characterization of the first Peacock-Weakley polyoxometalate containing a transplutonium element: curium bis-pentatungstate [Cm(W5O18)2]9.
Chem Commun (Camb)
; 60(47): 5999-6002, 2024 Jun 06.
Article
en En
| MEDLINE
| ID: mdl-38747262
ABSTRACT
Leveraging microgram-level techniques, we here present the first transplutonium bis-pentatungstate complex NaCs8Cm(W5O18)2·14H2O (CmW5). Single crystal XRD, Raman, and fluorescence characterization show significant differences relative to analogous lanthanide compounds. The study reveals the unsuspected impact of counterions on fluorescence and vibrational modes of the curium complex and its lanthanide counterparts.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2024
Tipo del documento:
Article
País de afiliación:
Estados Unidos