Dynamic negative allosteric effect: regulation of catalysis <i>via</i> multicomponent rotor speed.

Paul, Indrajit; Valiyev, Isa; Ghosh, Amit; Schmittel, Michael

Dynamic negative allosteric effect: regulation of catalysis via multicomponent rotor speed.

Paul, Indrajit; Valiyev, Isa; Ghosh, Amit; Schmittel, Michael.

Afiliación

Paul I; Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, School of Science and Technology, University of Siegen, Adolf-Reichwein-Str. 2, D-57068 Siegen, Germany. indrajitp763@gmail.com.
Valiyev I; Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, School of Science and Technology, University of Siegen, Adolf-Reichwein-Str. 2, D-57068 Siegen, Germany. indrajitp763@gmail.com.
Ghosh A; Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, School of Science and Technology, University of Siegen, Adolf-Reichwein-Str. 2, D-57068 Siegen, Germany. indrajitp763@gmail.com.
Schmittel M; Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, School of Science and Technology, University of Siegen, Adolf-Reichwein-Str. 2, D-57068 Siegen, Germany. indrajitp763@gmail.com.

Chem Commun (Camb) ; 60(55): 7085-7088, 2024 Jul 04.

Article en En | MEDLINE | ID: mdl-38896476

ABSTRACT

ABSTRACT

Nanorotor R1 (420 kHz) was assembled from five components utilizing three orthogonal interactions. Post-modification at the distal position generated the advanced six component rotor R2 (45 kHz). The decrease in R2 speed leads to the inhibition of a three-component reaction by reducing catalyst release.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Alemania

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