Structural Distortion of g-C3N4 Induced by a Schiff Base Reaction for Efficient Photocatalytic H2 Evolution.
Chem Asian J
; : e202400588, 2024 Jun 26.
Article
en En
| MEDLINE
| ID: mdl-38926300
ABSTRACT
Photocatalytic H2 evolution by water splitting is a promising approach to address the challenges of environmental pollution and energy scarcity. Graphitic carbon nitride (g-C3N4) has emerged as a star photocatalyst because of its numerous advantages. To address the limitations of traditional g-C3N4, namely its inadequate visible light response and rapid recombination of photogenerated carriers, we employed a schiff base reaction to synthesize -C=N- doped g-C3N4. The introduction of -C=N- groups at the bridging nitrogen sites induced structural distortion in g-C3N4, facilitating n-π* electronic transitions from the lone pair electrons of nitrogen atom and extending light absorption up to 600â
nm. Moreover, the presence of heterogeneous π-conjugated electron distribution effectively traps photogenerated electrons and enhances charge carrier separation. Benefiting from its expanded spectral response range, unique electronic properties, increased specific surface area, the doped g-C3N4 exhibited outstanding photocatalytic H2 evolution performance of 1050.13â
µmol/g/h. The value was 5.9 times greater than the pristine g-C3N4.
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01-internacional
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MEDLINE
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En
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Chem Asian J
Año:
2024
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Article