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High ammonia adsorption in copper-carboxylate materials: host-guest interactions and crystalline-amorphous-crystalline phase transitions.
Lu, Wanpeng; Chen, Yinlin; Wang, Zi; Guo, Lixia; Chen, Jin; Ma, Yujie; Li, Weiyao; Li, Jiangnan; He, Meng; Fan, Mengtian; Sheveleva, Alena M; Tuna, Floriana; McInnes, Eric J L; Frogley, Mark D; Chater, Philip A; Dejoie, Catherine; Schröder, Martin; Yang, Sihai.
Afiliación
  • Lu W; Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.
  • Chen Y; Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.
  • Wang Z; Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.
  • Guo L; College of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Sciences, Peking University, Beijing, 100871, China. Sihai.Yang@pku.edu.cn.
  • Chen J; Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.
  • Ma Y; Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.
  • Li W; Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.
  • Li J; College of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Sciences, Peking University, Beijing, 100871, China. Sihai.Yang@pku.edu.cn.
  • He M; Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.
  • Fan M; Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.
  • Sheveleva AM; Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.
  • Tuna F; Photon Science Institute, University of Manchester, Manchester, M13 9PL, UK.
  • McInnes EJL; Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.
  • Frogley MD; Photon Science Institute, University of Manchester, Manchester, M13 9PL, UK.
  • Chater PA; Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK. M.Schroder@manchester.ac.uk.
  • Dejoie C; Photon Science Institute, University of Manchester, Manchester, M13 9PL, UK.
  • Schröder M; Diamond Light Source, Harwell Science Campus, Oxfordshire, OX11 0DE, UK.
  • Yang S; Diamond Light Source, Harwell Science Campus, Oxfordshire, OX11 0DE, UK.
Chem Commun (Camb) ; 2024 Oct 07.
Article en En | MEDLINE | ID: mdl-39370930
ABSTRACT
We report the high NH3 uptake in a series of copper-carboxylate materials, namely MFM-100, MFM-101, MFM-102, MFM-126, MFM-127, MFM-190(F), MFM-170, and Cu-MOP-1a. At 273 K and 1 bar, MFM-101 shows an exceptional uptake of 21.9 mmol g-1. The presence of Cu(II)⋯NH3 interactions and changes in coordination at the [Cu2(O2CR)4] paddlewheel are analysed and discussed.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) / Chem. commun. (Lond., 1996, Online) / Chemical communications (London. 1996. Online) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) / Chem. commun. (Lond., 1996, Online) / Chemical communications (London. 1996. Online) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article
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