High ammonia adsorption in copper-carboxylate materials: host-guest interactions and crystalline-amorphous-crystalline phase transitions.
Chem Commun (Camb)
; 2024 Oct 07.
Article
en En
| MEDLINE
| ID: mdl-39370930
ABSTRACT
We report the high NH3 uptake in a series of copper-carboxylate materials, namely MFM-100, MFM-101, MFM-102, MFM-126, MFM-127, MFM-190(F), MFM-170, and Cu-MOP-1a. At 273 K and 1 bar, MFM-101 shows an exceptional uptake of 21.9 mmol g-1. The presence of Cu(II)â¯NH3 interactions and changes in coordination at the [Cu2(O2CR)4] paddlewheel are analysed and discussed.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
/
Chem. commun. (Lond., 1996, Online)
/
Chemical communications (London. 1996. Online)
Asunto de la revista:
QUIMICA
Año:
2024
Tipo del documento:
Article