Minimization of organocuprate complexity through self-organization: remarkable orientation effect in mixed cuprate π complexes.
Angew Chem Int Ed Engl
; 51(11): 2681-5, 2012 Mar 12.
Article
em En
| MEDLINE
| ID: mdl-22298492
ABSTRACT
They "know" where to go a powerful orientation effect has been observed in complexes of mixed organocuprates [R(T)R(NT)CuLi] and substrates with C-C, C-N, and C-S double bonds (see scheme; Th=thienyl). The preferred geometry of the intermediate complex sets up the facile addition of R(T) to the double bond, rather than addition of the "dummy ligand", R(NT) .
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Tipo de estudo:
Clinical_trials
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2012
Tipo de documento:
Article
País de afiliação:
Estados Unidos