[Study on the co-adsorption mechanism of Pb (II) and chlorpyrifos on arid loess in northwestern China].
Guang Pu Xue Yu Guang Pu Fen Xi
; 33(8): 2137-42, 2013 Aug.
Article
em Zh
| MEDLINE
| ID: mdl-24159863
ABSTRACT
The co-adsorption characteristics of Pb(II) and chlorpyrifos on arid loess were investigated with batch adsorption procedures, and the co-adsorption mechanism was studied with approaches of SEM, FT-IR, XRD and theoretical analysis. The experimental results indicated that the adsorption process of Pb(II) and chlorpyrifos on loess fit better the Langmuir isotherm, the maximum adsorption capacity of q(m) is 12.5 and 0.64 mg x g(-1) for Pb(II) and chlorpyrifos on loess, respectively, and the reaction could be illustrated with pseudo-second order kinetic equation. The SEM micrograph of loess surface varies little after the adsorption process of Pb(II) and chlorpyrifos, and certain wave peaks of FTIR spectra red-shift, disappears or intensity-decrease, with the XRD pattern and theoretical analysis, the adsorption mechanism is described as follows the adsorption of Pb (II) on arid loess is the chemical-effect of coordination-complexation and Van der Waals force; the physical-adsorption on chlorpyrifos involves the interception function, hydrogen bonds and Van der Waals force, and chemical adsorption effect to some extent. The organic matter in arid loess plays an important role in Pb(II) and chlorpyrifos adsorption.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
Zh
Revista:
Guang Pu Xue Yu Guang Pu Fen Xi
Ano de publicação:
2013
Tipo de documento:
Article
País de afiliação:
China