Iron-catalyzed acylation-oxygenation of terminal alkenes for the synthesis of dihydrofurans bearing a quaternary carbon.

Lv, Leiyang; Lu, Shenglin; Guo, Qiaoxia; Shen, Baojian; Li, Zhiping

Lv, Leiyang; Lu, Shenglin; Guo, Qiaoxia; Shen, Baojian; Li, Zhiping.

Afiliação

Lv L; Department of Chemistry, Renmin University of China, Beijing 100872, China.
Lu S; Department of Chemistry, Renmin University of China, Beijing 100872, China.
Guo Q; State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China.
Shen B; State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China.
Li Z; Department of Chemistry, Renmin University of China, Beijing 100872, China.

J Org Chem ; 80(1): 698-704, 2015 Jan 02.

Article em En | MEDLINE | ID: mdl-25424125

ABSTRACT

ABSTRACT

Iron-catalyzed acylation-oxygenation of terminal alkenes is reported. Acyl radicals generated by the oxidation of aldehydes add to terminal alkenes and followed by intramolecular oxygenation give functionalized 2,3-dihydrofuran derivatives bearing a quaternary carbon.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2015 Tipo de documento: Article País de afiliação: China

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