Heat Treatment for Regenerating Degraded Low-Dimensional Perovskite Solar Cells.
ACS Appl Mater Interfaces
; 10(5): 4860-4865, 2018 Feb 07.
Article
em En
| MEDLINE
| ID: mdl-29286626
ABSTRACT
Organolead halide perovskite devices are reported to be susceptible to thermal degradation, which results from heat-induced fast ion diffusion and structural decomposition. In this work, it is found that the performances of degraded low-dimensional perovskite solar cells can be considerably improved (e.g., power conversion efficiency shows â¼10% increase over the fresh device) by a short-time heat treatment (85 °C, 3 min). Capacitance-frequency, X-ray diffraction, and ionic diffusion calculation results suggest that heat treatment can enhance the crystallinity of the degraded low-dimensional perovskite and minimize the detrimental effects caused by water molecules, leading to improved performances. Our results indicate that the heat treatment does not necessarily lead to the accelerated degradation but can also regenerate the degraded low-dimensional perovskite.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
ACS Appl Mater Interfaces
Assunto da revista:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Ano de publicação:
2018
Tipo de documento:
Article