Effect of substituents on molybdenum triiodide complexes bearing PNP-type pincer ligands toward catalytic nitrogen fixation.

Itabashi, Takayuki; Mori, Ikki; Arashiba, Kazuya; Eizawa, Aya; Nakajima, Kazunari; Nishibayashi, Yoshiaki

Itabashi, Takayuki; Mori, Ikki; Arashiba, Kazuya; Eizawa, Aya; Nakajima, Kazunari; Nishibayashi, Yoshiaki.

Afiliação

Itabashi T; Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. ynishiba@sys.t.u-tokyo.ac.jp.

Dalton Trans ; 48(10): 3182-3186, 2019 Mar 05.

Article em En | MEDLINE | ID: mdl-30706067

ABSTRACT

ABSTRACT

Molybdenum triiodide complexes bearing various substituted pyridine-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward the reduction of nitrogen gas into ammonia under ambient reaction conditions.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Japão

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