Tantalum isocyanide complexes: TaI(CNDipp)6 (Dipp is 2,6-diisopropylphenyl) and ionic [Ta(CNDipp)7][Ta(CNDipp)6], a formal disproportionation product of the 17-electron Ta0 metalloradical Ta(CNDipp)6.

Brennessel, William W; Romanenkov, Alexander; Young, Victor G; Ellis, John E

Tantalum isocyanide complexes: TaI(CNDipp)₆ (Dipp is 2,6-diisopropylphenyl) and ionic [Ta(CNDipp)₇][Ta(CNDipp)₆], a formal disproportionation product of the 17-electron Ta⁰ metalloradical Ta(CNDipp)₆.

Brennessel, William W; Romanenkov, Alexander; Young, Victor G; Ellis, John E.

Afiliação

Brennessel WW; Department of Chemistry, University of Rochester, Rochester, NY 14627, USA.
Romanenkov A; Department of Chemistry, University of Minnesota, Minneapolis, NY 55455, USA.
Young VG; Department of Chemistry, University of Minnesota, Minneapolis, NY 55455, USA.
Ellis JE; Department of Chemistry, University of Minnesota, Minneapolis, NY 55455, USA.

Acta Crystallogr C Struct Chem ; 75(Pt 2): 135-140, 2019 Feb 01.

Article em En | MEDLINE | ID: mdl-30720451

Palavras-chave

2,6-diisopropylphenyl; crystal structure; homoleptic; isocyanide; low valent; monocapped trigonal prism; seven-coordinate; tantalum

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Acta Crystallogr C Struct Chem Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Estados Unidos

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