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Distannylated Bithiophene Imide: Enabling High-Performance n-Type Polymer Semiconductors with an Acceptor-Acceptor Backbone.
Shi, Yongqiang; Guo, Han; Huang, Jiachen; Zhang, Xianhe; Wu, Ziang; Yang, Kun; Zhang, Yujie; Feng, Kui; Woo, Han Young; Ortiz, Rocio Ponce; Zhou, Ming; Guo, Xugang.
Afiliação
  • Shi Y; School of New Energy and Materials and State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Engineering, Southwest Petroleum University, Chengdu, Sichuan, 610500, China.
  • Guo H; Department of Materials Science and Engineering, Southern University of Science and Technology (SUSTech), No. 1088, Xueyuan Road, Shenzhen, Guangdong, 518055, China.
  • Huang J; Department of Materials Science and Engineering, Southern University of Science and Technology (SUSTech), No. 1088, Xueyuan Road, Shenzhen, Guangdong, 518055, China.
  • Zhang X; Department of Materials Science and Engineering, Southern University of Science and Technology (SUSTech), No. 1088, Xueyuan Road, Shenzhen, Guangdong, 518055, China.
  • Wu Z; Department of Materials Science and Engineering, Southern University of Science and Technology (SUSTech), No. 1088, Xueyuan Road, Shenzhen, Guangdong, 518055, China.
  • Yang K; Department of Chemistry, College of Science, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul, 136-713, Republic of Korea.
  • Zhang Y; Department of Materials Science and Engineering, Southern University of Science and Technology (SUSTech), No. 1088, Xueyuan Road, Shenzhen, Guangdong, 518055, China.
  • Feng K; Department of Materials Science and Engineering, Southern University of Science and Technology (SUSTech), No. 1088, Xueyuan Road, Shenzhen, Guangdong, 518055, China.
  • Woo HY; Department of Materials Science and Engineering, Southern University of Science and Technology (SUSTech), No. 1088, Xueyuan Road, Shenzhen, Guangdong, 518055, China.
  • Ortiz RP; Department of Chemistry, College of Science, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul, 136-713, Republic of Korea.
  • Zhou M; Department of Physical Chemistry, University of Málaga, Campus de Teatinos s/n, Málaga, 29071, Spain.
  • Guo X; School of New Energy and Materials and State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Engineering, Southwest Petroleum University, Chengdu, Sichuan, 610500, China.
Angew Chem Int Ed Engl ; 59(34): 14449-14457, 2020 Aug 17.
Article em En | MEDLINE | ID: mdl-32472603
A distannylated electron-deficient bithiophene imide (BTI-Tin) monomer was synthesized and polymerized with imide-functionalized co-units to afford homopolymer PBTI and copolymer P(BTI-BTI2), both featuring an acceptor-acceptor backbone with high molecular weight. Both polymers exhibited excellent unipolar n-type character in transistors with electron mobility up to 2.60 cm2 V-1 s-1 . When applied as acceptor materials in all-polymer solar cells, PBTI and P(BTI-BTI2) achieved high power-conversion efficiency (PCE) of 6.67 % and 8.61 %, respectively. The PCE (6.67 %) of polymer PBTI, synthesized from the distannylated monomer, is much higher than that (0.14 %) of the same polymer PBTI*, synthesized from typical dibrominated monomer. The 8.61 % PCE of copolymer P(BTI-BTI2) is also higher than those (<1 %) of homopolymers synthesized from dibrominated monomers. The results demonstrate the success of BTI-Tin for accessing n-type polymers with greatly improved device performance.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2020 Tipo de documento: Article País de afiliação: China
Texto completo
Adicionar na Minha BVS
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XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2020 Tipo de documento: Article País de afiliação: China