PET-RAFT single unit monomer insertion of ß-methylstyrene derivatives: RAFT degradation and reaction selectivity.
Chem Commun (Camb)
; 57(82): 10759-10762, 2021 Oct 14.
Article
em En
| MEDLINE
| ID: mdl-34585689
ABSTRACT
Reversible addition-fragmentation chain transfer (RAFT) single unit monomer insertion (SUMI) of ß-methylstyrene derivatives into diverse RAFT agents presented fast reaction kinetics, but significant degradation of the SUMI products occurred due to a hydrogen abstraction reaction. Fortunately, such degradation can be suppressed through appropriate design of initial RAFT agents attributed to effective chain transfer and selective photoactivation.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2021
Tipo de documento:
Article
País de afiliação:
Austrália